Components of a wine's aroma.
Within wine there are volatile and non-volatile compounds that contribute to the make up of a wine's aroma. During the fermentation and for the first few months of a wine's existence, chemical reactions among these compounds occur frequently and a wine's aroma will change more rapidly during this period than at any other point. As a wine ages and matures, changes and developments in aroma will continue to take place but at a slower and more gradual pace. Volatile aroma compounds are present in the skin and juice of a grape berry and will vary in composition according to the individual grape variety. It is theorized that the Vitis vine developed these compounds as a evolutionary tool to aid in procreation by attracting insects to assist with pollination and birds and other animals to eat the berries and disperse the seeds. The diverse spectrum of aromas associated with individual grape varieties is a reflection of the vine's adaptation to ecological conditions and competition among other plants.
The majority of volatile compounds responsible for aroma combine with sugars in the wine to form odorless glycosides. Through the process of hydrolysis, caused by enzymes or acids in the wine, they revert into an aromatic form. The act of tasting wine is essentially the act of smelling these vaporized aroma compounds. Olfactory receptors cells, each sensitive to a different aromas, pick up these compounds and transfers the information to the brain by way of the olfactory bulb.[5] In the 1980s there was renewed focus in studying the correlation between aroma/flavor compounds in grapes and the resulting quality of wine. Scientists were able to use chromatograph-mass spectrometers to identify volatile aroma compounds in various grape varieties.
Study of the compounds responsible for aroma and flavor, as well as their correlation with a wine's quality, is ongoing. As understanding of these compounds grows, there is concern that wines in the future could be "manipulated" through the use of chemical additives to add complexity and additional aromas to wine (such as creating a manufactured perfume) . In 2004, a winery in South Africa was found to have added illegal flavoring to their Sauvignon blanc to enhance the aroma. Viticultural studies have focused on how aroma compounds develop in the grapes during the annual growth cycle of the vine and how viticultural techniques such as canopy management may contribute to developing desirable aromatics in the wine.
Identified aroma compounds
Some of the identified aroma compounds include the following:
Some of the aromas perceived in wine are from esters created by the reaction of acids and alcohol in the wine. Esters can develop during fermentation, with the influence of yeast, or later during aging by chemical reactions. The precise yeast strain used during fermentation and temperature are two of the strongest indicators of what kind of esters will develop and helps explain partially why Chardonnay grown in the same vineyard but made by two different producers could have different aromatics. During bottle aging hydrogen ions, found in higher concentration in low pH (high acid) wines, serves as a catalyst in the formation of esters from acids and alcohols present in the wine. However, at the same time these hydrogen ions encourage esters to also split apart back into acids and alcohols. These two counterbalancing acts gradually inch a wine closer to a state of equilibrium where there is equal parts alcohol, acids, esters and water (a by product of the reactions). During this period the ester influenced bouquet of the wine is constantly changing due to the concentration, formulation and splitting of different esters. This is partly the reason why a wine will have one set of aromas at one time and other aromas later in its life.
Aroma vs. bouquet.
In professional wine tasting, there is generally a distinction made between "aromas" and a wine's "bouquet" while in casual wine tasting these two terms are used interchangeably. An aroma refers to the smells unique to the grape variety and are most readily demonstrated in a varietal wine--such as lychees with Gewürztraminer or black currant with Cabernet Sauvignon. These are smells that are commonly associated with a young wine. As a wine ages chemical reactions among acids, sugars, alcohols and phenolic compounds create new smells that are known as a wine's bouquet. These can include honey in an aged Sauternes or truffles in a Pinot noir. The term bouquet can also be expanded to include the smells derived from fermentation and exposure to oak. In Burgundy, the aromas of wines are sub-divided into three categories-primary, secondary and tertiary aromas. Primary aromas are those specific to the grape variety itself. Secondary aromas are those derived from fermentation and oak aging. Tertiary aromas are those that develop through bottled aging.[2] The technique of microoxygenation has an impact on the aromatic bouquet.
courtesy of www.globalwinefair.com
Within wine there are volatile and non-volatile compounds that contribute to the make up of a wine's aroma. During the fermentation and for the first few months of a wine's existence, chemical reactions among these compounds occur frequently and a wine's aroma will change more rapidly during this period than at any other point. As a wine ages and matures, changes and developments in aroma will continue to take place but at a slower and more gradual pace. Volatile aroma compounds are present in the skin and juice of a grape berry and will vary in composition according to the individual grape variety. It is theorized that the Vitis vine developed these compounds as a evolutionary tool to aid in procreation by attracting insects to assist with pollination and birds and other animals to eat the berries and disperse the seeds. The diverse spectrum of aromas associated with individual grape varieties is a reflection of the vine's adaptation to ecological conditions and competition among other plants.
The majority of volatile compounds responsible for aroma combine with sugars in the wine to form odorless glycosides. Through the process of hydrolysis, caused by enzymes or acids in the wine, they revert into an aromatic form. The act of tasting wine is essentially the act of smelling these vaporized aroma compounds. Olfactory receptors cells, each sensitive to a different aromas, pick up these compounds and transfers the information to the brain by way of the olfactory bulb.[5] In the 1980s there was renewed focus in studying the correlation between aroma/flavor compounds in grapes and the resulting quality of wine. Scientists were able to use chromatograph-mass spectrometers to identify volatile aroma compounds in various grape varieties.
Study of the compounds responsible for aroma and flavor, as well as their correlation with a wine's quality, is ongoing. As understanding of these compounds grows, there is concern that wines in the future could be "manipulated" through the use of chemical additives to add complexity and additional aromas to wine (such as creating a manufactured perfume) . In 2004, a winery in South Africa was found to have added illegal flavoring to their Sauvignon blanc to enhance the aroma. Viticultural studies have focused on how aroma compounds develop in the grapes during the annual growth cycle of the vine and how viticultural techniques such as canopy management may contribute to developing desirable aromatics in the wine.
Identified aroma compounds
Some of the identified aroma compounds include the following:
- Methoxypyrazine-grassy, herbaceous aroma compound associated with Cabernet Sauvignon and Sauvignon blanc.
- Monoterpenes-responsible for the floral aromatics of varieties like Gewürztraminer, Muscat and Riesling. Includes geraniol, linalool and nerol.
- Norisoprenoids-Carotenoid derived aromatic compounds[6] that includes megastigmatrienone which produces some of the spice notes associated with Chardonnay and zingerone responsible for the different spice notes associated with Syrah. Other norisoprenoids include raspberry ketone which produces some of the raspberry aromas associated with red wine, damascenone which produces some of the rose oil aromas associated with Pinot noir and vanillin.
- Thiols-sulfur contain compounds that can produce an aroma of garlic and onion that is considered a wine fault (mercaptans). They have also been found to contribute to some of the varietal aromas associated with Cabernet Sauvignon, Gewürztraminer, Merlot, Muscat, Petit Manseng, Pinot blanc, Pinot gris, Riesling, Scheurebe, Semillon and Sylvaner.
Some of the aromas perceived in wine are from esters created by the reaction of acids and alcohol in the wine. Esters can develop during fermentation, with the influence of yeast, or later during aging by chemical reactions. The precise yeast strain used during fermentation and temperature are two of the strongest indicators of what kind of esters will develop and helps explain partially why Chardonnay grown in the same vineyard but made by two different producers could have different aromatics. During bottle aging hydrogen ions, found in higher concentration in low pH (high acid) wines, serves as a catalyst in the formation of esters from acids and alcohols present in the wine. However, at the same time these hydrogen ions encourage esters to also split apart back into acids and alcohols. These two counterbalancing acts gradually inch a wine closer to a state of equilibrium where there is equal parts alcohol, acids, esters and water (a by product of the reactions). During this period the ester influenced bouquet of the wine is constantly changing due to the concentration, formulation and splitting of different esters. This is partly the reason why a wine will have one set of aromas at one time and other aromas later in its life.
Aroma vs. bouquet.
In professional wine tasting, there is generally a distinction made between "aromas" and a wine's "bouquet" while in casual wine tasting these two terms are used interchangeably. An aroma refers to the smells unique to the grape variety and are most readily demonstrated in a varietal wine--such as lychees with Gewürztraminer or black currant with Cabernet Sauvignon. These are smells that are commonly associated with a young wine. As a wine ages chemical reactions among acids, sugars, alcohols and phenolic compounds create new smells that are known as a wine's bouquet. These can include honey in an aged Sauternes or truffles in a Pinot noir. The term bouquet can also be expanded to include the smells derived from fermentation and exposure to oak. In Burgundy, the aromas of wines are sub-divided into three categories-primary, secondary and tertiary aromas. Primary aromas are those specific to the grape variety itself. Secondary aromas are those derived from fermentation and oak aging. Tertiary aromas are those that develop through bottled aging.[2] The technique of microoxygenation has an impact on the aromatic bouquet.
courtesy of www.globalwinefair.com
